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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 22
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Original Articles

Tin Effects in the Hydroboration of Hindered Olefins

James A. Akers Department of Chemistry, University of South Carolina, Columbia, SC, 29208
&
Thomas A. Bryson Department of Chemistry, University of South Carolina, Columbia, SC, 29208
Pages 3453-3458 | Received 08 Oct 1990, Published online: 24 Oct 2006
 
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Abstract

Intermolecular hydroboration of tetrasubstituted olefins is enhanced by allylic tin substituents. Intramolecular hydroboration using hindered allylic tin substrates is found to be inefficient presumably due to the steric bulk of the trialkylstannane group.

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