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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 5
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Original Articles

Oxidation of Benzylic and Secondary Alcohols Using m-Chloroperbenzoic Acid/Hydrogen Chloride/N,N-Dimethylformamide System

Hyoung Rae Kim Division of Organic Chemistry, Korea Research Institute of Chemical Technology, P.O. Box 9 Daedeog-Danji, Daejeon, 305‐606, Korea
,
Ji Hun Jung Division of Organic Chemistry, Korea Research Institute of Chemical Technology, P.O. Box 9 Daedeog-Danji, Daejeon, 305‐606, Korea
,
Jae Nyong Kim Division of Organic Chemistry, Korea Research Institute of Chemical Technology, P.O. Box 9 Daedeog-Danji, Daejeon, 305‐606, Korea
&
Eung K. Ryu Division of Organic Chemistry, Korea Research Institute of Chemical Technology, P.O. Box 9 Daedeog-Danji, Daejeon, 305‐606, Korea
Pages 637-640 | Received 18 Oct 1989, Published online: 24 Oct 2006
 
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Abstract

The oxidation of benzylic and secondary alcohols with MCPBA in the presence of a catalytic amount of HCl in DMF leads to the corresponding aldehydes and ketones in excellent yields.

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