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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 3
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Original Articles

Hydroperoxide Oxidations of α-(N, N-Dialkylamino)amides

David Wenkert Department of Chemistry, North Texas State University, Denton, TX, 76203-5068; Saint Louis Childrens' Hospital, Washington University Medical Center, 400 South Kingshighway Blvd., Saint Louis, Missouri, 63110
,
E. Charles Angell Department of Chemistry, North Texas State University, Denton, TX, 76203-5068
,
Tse-Fang Chen Department of Chemistry, North Texas State University, Denton, TX, 76203-5068
&
Kishore Ramachandran Department of Chemistry, North Texas State University, Denton, TX, 76203-5068
Pages 447-457 | Received 09 Oct 1989, Published online: 24 Oct 2006
 
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Abstract

m-Chloroperbenzoic acid oxidation of α-(N,N-Dialkylamino)-amides gives the respective N-oxides, whereas hydrogen peroxide oxidation results in the production of N-formylamides. A mechanism for the latter observation that is presented.

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