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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 9
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Original Articles

Chiral Organosilicon Compounds, Part 3. Peracid Oxidation of Chiral Silyl Enol Ethers

Perry T. Kaye Department of Chemistry, Rhodes University, P.O. Box 94, Grahamstown, 6140, Republic of South Africa
&
Robin A. Learmonth Department of Chemistry, Rhodes University, P.O. Box 94, Grahamstown, 6140, Republic of South Africa
Pages 1333-1338 | Received 02 Feb 1990, Published online: 24 Oct 2006
 
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Abstract

MCPBA oxidation of selected chiral silyl enol ethers proceeds with migration of the chiral auxilliary to afford diastereomeric α-siloxyketones.

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