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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 12
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Original Articles

Ion Exchange Resin-Mediated Hydrolytic Cleavage of Epoxides. Simple One-Pot Synthesis of 2-Arylketones from 1-Aryl-1,2-epoxides

Brindaban C. Ranu Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700 032, INDIA
&
Rupak Chakraborty Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700 032, INDIA
Pages 1751-1756 | Received 13 Mar 1990, Published online: 24 Oct 2006
 
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Abstract

Epoxides are cleaved in an aqueous solution with Dowex-50W. Alicyclic epoxides are converted to trans-1,2-diols whereas 1-aryl-1,2-epoxides furnish 2-arylketones in excellent yields.

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