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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 12
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Original Articles

Synthesis of 2,2-DiaIkyl-3-HaIopropannitriles from 2,2-Dialkylethanenitrles and Dihalomethanes

Ian A. Cliffe Department of Medicinal Chemistry, Wyeth Research (U.K.) Huntercombe Lane South, Taplow, Maidenhead, Berkshire, SL6 OPH, England
,
Richard S. Todd Department of Medicinal Chemistry, Wyeth Research (U.K.) Huntercombe Lane South, Taplow, Maidenhead, Berkshire, SL6 OPH, England
&
Alan C. White Department of Medicinal Chemistry, Wyeth Research (U.K.) Huntercombe Lane South, Taplow, Maidenhead, Berkshire, SL6 OPH, England
Pages 1757-1767 | Received 14 Mar 1990, Published online: 24 Oct 2006
 
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Abstract

A simple high-yielding synthesis of 2,2-dialkyl-3-halopropanenitriles is described which involves the alkylation of 2,2-dialkylethanenitriles with bromochloromethane.

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