Oxidation of Aryl Alkyl Ketones To α-Acyloxy, α-(Camphorsulfonyloxy), or α-Hydroxy Derivatives Using Manganese(III) Acetate in Combination with Carboxylic Acids or (1S)-(+)-10-Camphorsulfonic Acid

Ayhan S. Demir Department of Chemistry, Middle East Technical University, 06531, Ankara, Turkey

Nurettin Camkerten Department of Chemistry, Middle East Technical University, 06531, Ankara, Turkey

Hulya Akgun Department of Chemistry, Middle East Technical University, 06531, Ankara, Turkey

Cihangir Tanyeli Department of Chemistry, Middle East Technical University, 06531, Ankara, Turkey

Ali S. Mahasneh Department of Chemistry, Middle East Technical University, 06531, Ankara, Turkey

David S. Watt Department of Chemistry, University of Kentucky, Lexington, KY, 40506

Abstract

The α-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, α-(10-camphorsulfonyloxy), and α-hydroxy derivatives in good yield.

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Oxidation of Aryl Alkyl Ketones To α-Acyloxy, α-(Camphorsulfonyloxy), or α-Hydroxy Derivatives Using Manganese(III) Acetate in Combination with Carboxylic Acids or (1S)-(+)-10-Camphorsulfonic Acid

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Oxidation of Aryl Alkyl Ketones To α-Acyloxy, α-(Camphorsulfonyloxy), or α-Hydroxy Derivatives Using Manganese(III) Acetate in Combination with Carboxylic Acids or (1S)-(+)-10-Camphorsulfonic Acid

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