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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 16
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Original Articles

Synthesis of Trans-Carah-4-Carboxylic Acids

, &
Pages 2507-2517 | Received 15 Jun 1990, Published online: 24 Oct 2006
 

Abstract

The synthesis of the optically active transcaran-4-carboxylic acids 4a and 5a is reported. Methylene-cis-and trans-caranes (8) and (9) were prepared by Wittig reaction from (-)-cis-caran-4-one (6). The structure of the described compounds are supported by chemical evidence.

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