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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 16
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Original Articles

Regioselective Synthesis of 2-Functionalized Thiophenes by Condensation of α-Mercapto Compounds with β-Aminoenone Derivatives

Angel Alberola Departamento de Quimica Orgãnica. Facultad de Ciencias, Universidad de Valladolid, 47011, Valladolid, Spain
,
José M. Andrés Departamento de Quimica Orgãnica. Facultad de Ciencias, Universidad de Valladolid, 47011, Valladolid, Spain
,
Alfonso Gonzãlez Departamento de Quimica Orgãnica. Facultad de Ciencias, Universidad de Valladolid, 47011, Valladolid, Spain
,
Rafael Pedrosa Departamento de Quimica Orgãnica. Facultad de Ciencias, Universidad de Valladolid, 47011, Valladolid, Spain
&
Pedro Prãdanos Departamento de Quimica Orgãnica. Facultad de Ciencias, Universidad de Valladolid, 47011, Valladolid, Spain
Pages 2537-2547 | Received 22 Jun 1990, Published online: 24 Oct 2006
 
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Abstract

2-Acylthiophenes and ethyl 2-thiophene-carboxylates are prepared regioselectively by reaction of 3-ctil oroenones and 2-acylenammoni urn chlorides with α-mercapto derivatives in good to moderate yields.

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