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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 1
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Original Articles

Control of Regiochemistry, Stereochemistry and Stoichiometry in Additions to Alkadiynes. Synthetic Value of a Sulfone Function

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Pages 53-61 | Received 02 Aug 1989, Published online: 24 Oct 2006
 

Abstract

The strategic placement of a sulfone function alpha to a conjugated alkadiyne is shown to enforce total control of regiochemistry, stereochemistry and stoichiometry in additions of nucleophiles across the triple bonds.

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