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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 1
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Original Articles

Reduction of Isophorone With Sodium Borohydride: Change in Regioselectivity with Hydrotropes

Mahalaxmi Laxman Department of Chemical Technology, University of Bombay, Matunga, Bombay, 400 019, India
&
Man Mohan Sharma Department of Chemical Technology, University of Bombay, Matunga, Bombay, 400 019, India
Pages 111-117 | Received 09 Aug 1989, Published online: 24 Oct 2006
 
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Abstract

Preferential 1,4- reduction of isophorone by sodium borohydride occurs in the presence of hydrotropes such as polyalkylene glycols. An anomalous effect of temperature was also observed using sodium salicylate as hydrotrope.

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