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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 4
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Original Articles

Chlorination of Alkenes with MnO2-MnCl2-Acetyl Chloride in Dimethyl Formamide

Franco Bellesia Dipartimento di Chimica, dell 'Università, Via Campi 183, I-41100, Modena, Italy
,
Franco Ghelfi Dipartimento di Chimica, dell 'Università, Via Campi 183, I-41100, Modena, Italy
,
Ugo M. Pagnoni Dipartimento di Chimica, dell 'Università, Via Campi 183, I-41100, Modena, Italy
&
Adriano Pinetti Dipartimento di Chimica, dell 'Università, Via Campi 183, I-41100, Modena, Italy
Pages 489-494 | Received 13 Dec 1990, Published online: 23 Sep 2006
 
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Abstract

Chlorination of alkenes was achieved in high yields by MnO2-MnCl2-Acetyl Chloride in dimethylformamide. A Mn(III) intermediate and a ligand-transfer process are suggested.

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