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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 2
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Original Articles

Synthesis of α-Hetero Atom Substituted β-Keto and Enamine Phosphonates

Kilsung Lee Department of Chemistry Korea Advanced, Institute of Science & Technology, P.O. Box 150, Cheongyang-ni, Seoul, 130-650, Korea
&
Dong Young Oh Department of Chemistry Korea Advanced, Institute of Science & Technology, P.O. Box 150, Cheongyang-ni, Seoul, 130-650, Korea
Pages 279-284 | Received 27 Nov 1990, Published online: 23 Sep 2006
 
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Abstract

Various α-hetero atom substituted β-keto and enamine phosphonates are prepared by the nucleophilic addition of α-lithioanion of diethyl methylphosphonate to nitriles followed by subsequent addition of electrophiles.

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