A New Simple and Industrial Process for Bromination of Alcohols

Jean-Manuel Mas Rhône-Poulenc, Centre de Recherches des Carrières, 85, avenue des Frères Perret, BP. 62, 69192, Saint-Fons, Cedex, FRANCE

Pascal Metivier Rhône-Poulenc, Centre de Recherches des Carrières, 85, avenue des Frères Perret, BP. 62, 69192, Saint-Fons, Cedex, FRANCE

Abstract

Alcohols treated with thionyl chloride, followed by chlorine/bromine exchange using gaseous hydrobromic acid and thermal decomposition in the presence of a tertiary amine give the corresponding brominated compounds. The process is regio/stereo selective.

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A New Simple and Industrial Process for Bromination of Alcohols

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A New Simple and Industrial Process for Bromination of Alcohols

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