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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 15
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Original Articles

An Efficient Synthesis of 1-Allyl-1-Cyano-1-Alkenes and Related Structures

Bernard MAUZÉ Laboratoire de Synthèse Organique, Associé au CNRS, Université de Poitiers, 40, avenue du Recteur Pineau, 86022, Poitiers, France
&
Léone Miginiac Laboratoire de Synthèse Organique, Associé au CNRS, Université de Poitiers, 40, avenue du Recteur Pineau, 86022, Poitiers, France
Pages 2229-2235 | Received 02 Apr 1992, Published online: 24 Sep 2006
 
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Abstract

The one-pot synthesis of 1-allyl-1-cyano-1-alkenes is easily obtained from 1-allyl-1-trimethylsilylacetonitrile lithium and carbonyl derivatives via a silyl-Wittig-Peterson reaction. Other related compounds are prepared in the same manner.

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