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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 12
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Original Articles

Access to Protected Functional Aldehydes by Free Radical Additions to Acrolein Diethylacetal

M. Degueil-Casting Laboratiore de Chimie Organique et Organométallique, associé au CNRS (URA 35), Université Bordeaux 1, F-33405, Talence, Cedex, FRANCE
,
K. Mohr Laboratiore de Chimie Organique et Organométallique, associé au CNRS (URA 35), Université Bordeaux 1, F-33405, Talence, Cedex, FRANCE
&
B. Maillard Laboratiore de Chimie Organique et Organométallique, associé au CNRS (URA 35), Université Bordeaux 1, F-33405, Talence, Cedex, FRANCE
Pages 1703-1712 | Received 04 Feb 1992, Published online: 23 Sep 2006
 
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Abstract

Free radical additions of hydrogen donor solvents (cyclohexane, dichloromethan, tetrahydrofuran, demethyl malonate and pentan-2-one) to acrolein diethylacetal allowed their 3, 3 diethoxypropylation.

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