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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 12
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Original Articles

A Cyclic Sulfate Approach to the Synthesis of 1,4-Dideoxy-1,4-imino Derivatives of L-Xylitol, L-Arabinitol and D-Xylitol

Pieter A.M. van der Klein Gorlaeus Laboratories, P.O. Box 9502, 2300, RA, Leiden, The Netherlands
,
Wim Filemon Gorlaeus Laboratories, P.O. Box 9502, 2300, RA, Leiden, The Netherlands
,
Helgo J.G. Broxterman Gorlaeus Laboratories, P.O. Box 9502, 2300, RA, Leiden, The Netherlands
,
Gijs A. van der Marel Gorlaeus Laboratories, P.O. Box 9502, 2300, RA, Leiden, The Netherlands
&
Jacques H. van Boom Gorlaeus Laboratories, P.O. Box 9502, 2300, RA, Leiden, The Netherlands
Pages 1763-1771 | Accepted 18 Feb 1992, Published online: 23 Sep 2006
 
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Abstract

Polyhydroxylated pyrrolidines are readily accessible by ring opening of a 1,4-cyclic sulfate function in pentitol derivatives by nitrogen nucleophiles and further processing of the in situ generated charged sulfate group.

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