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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 13
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Original Articles

Longifolene as a Chiron: Extraction of the Bicyclic Core of the Spongian-Type Diterpenoids

Goverdhan Mehta School of Chemistry, University of Hyderabad, Hyderabad, 500 134, India
&
Abraham Thomas School of Chemistry, University of Hyderabad, Hyderabad, 500 134, India
Pages 1831-1838 | Accepted 14 Feb 1992, Published online: 23 Sep 2006
 
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Abstract

A short degradation of (+)-longifolene 1 to hydroazulene (+)-9 is described. Restructuring of 1 to a novel tricyclic framework (−)-10 is also reported.

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