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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 13
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Original Articles

A New Efficient and Stereoselective Synthesis of 1,3E,5Z-Undecatriene

Alex Alexakis Laboratoire de Chimie des Organo-Eléments, CNRS UA 473 Université P. et M. Curie, 4, Place Jussieu, F-75252, Paris Cedex 05, France
,
Anne-Marie Barthel
,
Jean F. Normant Laboratoire de Chimie des Organo-Eléments, CNRS UA 473 Université P. et M. Curie, 4, Place Jussieu, F-75252, Paris Cedex 05, France
,
Claude Fugier Laboratoires de Recherche Oril S.A., F-76210, Bolbec, France
&
Michel Leroux
Pages 1839-1844 | Accepted 20 Feb 1992, Published online: 23 Sep 2006
 
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Abstract

1,3E,5Z-Undecatriene is synthesized by coupling of Z-heptenyl copper reagent, obtained through carbocupration of acetylene, with 1-chloro-1E,3-butadiene, in the presence of 5% NiCl2(PPh3)2

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