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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 14
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Original Articles

Bistriphenylsilanol-Assisted Oxidation Catalyzed by Chromium(VI) Oxide of Activated Trimethylsilyl Ethers with tert-Butyl Hydroperoxide

Jacques Muzart Unité de Recherche “Réarrangements Thermiques et Photochimiques” Associée au C.N.R.S, Université de Reims Champagne-Ardenne, B.P. 347, 51062, Reims Cedex, France
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Abdelaziz N'Ait Ajjou Unité de Recherche “Réarrangements Thermiques et Photochimiques” Associée au C.N.R.S, Université de Reims Champagne-Ardenne, B.P. 347, 51062, Reims Cedex, France
Pages 1993-1996 | Accepted 06 Mar 1992, Published online: 23 Sep 2006
 
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Abstract

Secondary benzylic or allylic trimethylsilyl ethers are oxidized at room temperature to the corresponding ketones in good yields using aqueous 70% t-BuOOH and catalytic amounts of a mixture of Ph3SiOH and CrO3.

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