A Practical 2,3-Pyridyne Precursor

Michael A. Walters Department of Chemistry, Dartmouth College, 6128 Steele Hall, Hanover, New Hampshire, 03755-3577

Percy H. Carter Department of Chemistry, Dartmouth College, 6128 Steele Hall, Hanover, New Hampshire, 03755-3577

Satyajit Banerjee Department of Chemistry, Dartmouth College, 6128 Steele Hall, Hanover, New Hampshire, 03755-3577

Abstract

3-Bromo-2-chloro-4-methoxypyridine has been developed as a practical 2,3-pyridyne precursor. The substituted 2,3-pyridyne generated from this precursor by halogen-metal exchange has been found to react regioselectively with 2-methoxyfuran and 2-methylfuran.

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A Practical 2,3-Pyridyne Precursor

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