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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 23, 1993 - Issue 9
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Original Articles

Enantioselective Approaches to Rhodium Catalysed Aldol-Type Reactions

Gregory H. P. Roos Department of Chemistry, University of Natal, P. O. Box 375, Pietermaritzburg, 3200, South Africa
,
Raymond J. Haines Department of Chemistry, University of Natal, P. O. Box 375, Pietermaritzburg, 3200, South Africa
&
Conrad E. Raab Department of Chemistry, University of Natal, P. O. Box 375, Pietermaritzburg, 3200, South Africa
Pages 1251-1259 | Received 16 Nov 1992, Published online: 24 Sep 2006
 
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Abstract

Homochiral catalysts, [Rh (norbornadiene)-(homochiral diphosphine)]+ X−/H2, were tested to assess possible enantiocontrol in the aldol-type coupling of activated vinyl components with aldehydes. A related approach, via in situ rhodium silyl enolates, was also investigated.

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