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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 23, 1993 - Issue 11
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Original Articles

Silica Gel Catalysed Rearrangement of α-Epoxyketones to 1,2-Diketones

T. Bharati Rao Regional Research Laboratory (CSIR), Trivandrum, 695019, India
&
J. Madhusudana Rao Regional Research Laboratory (CSIR), Trivandrum, 695019, India
Pages 1527-1533 | Received 16 Nov 1992, Published online: 23 Sep 2006
 
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Abstract

A convenient and simple method for the preparation of diphenylpropane-1,2-diones is described. The process involves rearrangement of α-epoxyketones on silica gel; an unusual migration of a proton instead of the more common benzoyl migration.

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