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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 24, 1994 - Issue 1
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Original Articles

Synthesis of β-Keto-phosphotriesters Using Functionalized Diazoketones

T. Gefflaut Groupe de Chimie Organique Biologique, URA 470, Bat IIR1 Université Paul Sabatier, 118 route de, Narbonne, 31062, Toulouse
&
Jacques Périé Groupe de Chimie Organique Biologique, URA 470, Bat IIR1 Université Paul Sabatier, 118 route de, Narbonne, 31062, Toulouse
Pages 29-33 | Received 04 Jun 1993, Published online: 23 Sep 2006
 
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Abstract

Convenient substitution (Ac) on the heteroatom in diazo ketones as in compounds 6, 8 or 10, prevents the classical cyclisation reaction and allows intermolecular addition; the reaction is applied to phosphorylation (reaction 1).

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