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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 24, 1994 - Issue 5
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Original Articles

Reductive Electrophilic Substitution of Diarylmethyl Methyl Ethers: Synthetic Applications

Ugo Azzena Dipartimento di Chimica, Università di Sassari, via Vienna 2, I-07100, Sassari
,
Giovanni Melloni Dipartimento di Chimica, Università di Sassari, via Vienna 2, I-07100, Sassari
,
Emma Fenude Istituto A. T. C. A. P. A., C. N. R., via Vienna 2, I-07100, Sassari, Italy
,
Clara Finà Istituto A. T. C. A. P. A., C. N. R., via Vienna 2, I-07100, Sassari, Italy
,
Mauro Marchetti Istituto A. T. C. A. P. A., C. N. R., via Vienna 2, I-07100, Sassari, Italy
&
Barbara Sechi Istituto A. T. C. A. P. A., C. N. R., via Vienna 2, I-07100, Sassari, Italy
Pages 591-599 | Received 10 Aug 1993, Published online: 23 Sep 2006
 
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Abstract

The reductive cleavage of diarylmethyl methyl ethers with Li metal in THF led to quantitative formation of the corresponding diarylmethyl anions. Quenching with electrophiles afforded substituted diarylmethanes in good to excellent yields.

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