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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 24, 1994 - Issue 2
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Original Articles

A Novel Method of Arylation of α-Chloroketones

Muriel Durandetti Laboratoire d'Electrochimie, Catalyse et Synthèse Organique, CNRS, UMR 28, 2, Rue Henri Dunant, 94320, Thiais, France
,
Soline Sibille Laboratoire d'Electrochimie, Catalyse et Synthèse Organique, CNRS, UMR 28, 2, Rue Henri Dunant, 94320, Thiais, France
,
Jean-Yves Nédélec Laboratoire d'Electrochimie, Catalyse et Synthèse Organique, CNRS, UMR 28, 2, Rue Henri Dunant, 94320, Thiais, France
&
Jacques Périchon Laboratoire d'Electrochimie, Catalyse et Synthèse Organique, CNRS, UMR 28, 2, Rue Henri Dunant, 94320, Thiais, France
Pages 145-151 | Received 01 Jul 1993, Published online: 23 Sep 2006
 
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Abstract

α-Arylated ketones were obtained in moderate to good yields by one-step electroreductive coupling of α-chloroketones and arylhalides in DMF and in the presence of a Al- or Zn-sacrificial anode and a catalytic amount of a nickel complex.

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