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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 2
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Original Articles

Alkylation of Diethyl Acetamidomalonate by Weak Electrophiles

Jiarong Zhu Laboratoire de Chimie Organique, FaculteÉ de Pharmacie, 4, avenue de l′Observatoire, 75270, Paris, France
,
Hervc Galons Laboratoire de Chimie Organique, FaculteÉ de Pharmacie, 4, avenue de l′Observatoire, 75270, Paris, France
,
Philippe Pigeon Laboratoire des Reéactions Seélectives sur Supports, ICMO, UA 478, CNRS Universiteé de Paris Sud, Ba[acaron] 410, Orsay Ceédex, France
&
André Loupy Laboratoire des Reéactions Seélectives sur Supports, ICMO, UA 478, CNRS Universiteé de Paris Sud, Ba[acaron] 410, Orsay Ceédex, France
Pages 215-218 | Received 13 May 1994, Published online: 23 Sep 2006
 
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Abstract

Diethyl acetamidomalonate was efficiently alkylated with electrophiles of low reactivity under modified phase transfer-catalysis conditions in the absence of organic solvent using potassium tert-butoxide as a base.

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