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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 2
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Original Articles

Facile Tandem Michael Addition-Retro Dieckmann Reaction of Cyclic β-Ketoesters: One-Pot Preparation of Polyfunctionalized Acyclic Derivatives

Marie-Héléne Filippini Laboratoire de Synthèse OrganiqueSM B URA 1411 Universitéd′Aix- Marseille III, Faculté des Sciences de St Jéróme D 12, Avenue Escadrille Normandie-Niemen, 13397, Marseille cedex, 20, France
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Jean Rodriguez Laboratoire de Synthèse OrganiqueSM B URA 1411 Universitéd′Aix- Marseille III, Faculté des Sciences de St Jéróme D 12, Avenue Escadrille Normandie-Niemen, 13397, Marseille cedex, 20, France
Pages 245-252 | Received 19 May 1994, Published online: 23 Sep 2006
 
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Abstract

A facile base promoted tandem Michael addition-retro Dieckmann reaction leading to polyfunctionalized acyclic derivatives is observed by condensation of β-ketoesters with α,β-unsaturated electrophiles in methanol.

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