Components of the Sex Pheromone of Chilo Supressalis: Efficient Syntheses of (Z)-11-Hexadecenal and (Z)-13-Octadecenal

S. Gil Departamento de Química Orgánica, Facultad de Química, Universitat de Valencia Dr. Moliner 50, BURJASSOT (Valencia), SPAIN

M. A. Lázaro Departamento de Química Orgánica, Facultad de Química, Universitat de Valencia Dr. Moliner 50, BURJASSOT (Valencia), SPAIN

R. Mestres Departamento de Química Orgánica, Facultad de Química, Universitat de Valencia Dr. Moliner 50, BURJASSOT (Valencia), SPAIN

F. Millan Departamento de Química Orgánica, Facultad de Química, Universitat de Valencia Dr. Moliner 50, BURJASSOT (Valencia), SPAIN

M. Parra Departamento de Química Orgánica, Facultad de Química, Universitat de Valencia Dr. Moliner 50, BURJASSOT (Valencia), SPAIN

Abstract

(Z)-11-Hexedecenal 1a and (Z)-13-octadecenenal 2a, components of the sex attractant pheromone of Chilo supressalis, have been synthesized as their ethylene acetals 1b and 2b from cyclododecanone 3, through intermediacy of the C₁₂ ω functionalized acetals 8 and 12.

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Components of the Sex Pheromone of Chilo Supressalis: Efficient Syntheses of (Z)-11-Hexadecenal and (Z)-13-Octadecenal

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Components of the Sex Pheromone of Chilo Supressalis: Efficient Syntheses of (Z)-11-Hexadecenal and (Z)-13-Octadecenal

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