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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 19
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Original Articles

Stereoselective Synthesis of Some Dialkyl (E)-2-Bromomethylene Glutarates

T. Ben Ayed Laboratoire de Chimie Organique et Organométallique, Faculté des Sciences Campus Universitaire, 1060, Tunis -TUNISIE
,
M. M. El Gaïed Laboratoire de Chimie Organique et Organométallique, Faculté des Sciences Campus Universitaire, 1060, Tunis -TUNISIE
&
H. Amri Laboratoire de Chimie Organique et Organométallique, Faculté des Sciences Campus Universitaire, 1060, Tunis -TUNISIE
Pages 2981-2987 | Received 14 Feb 1995, Published online: 16 Feb 2007
 
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Abstract

Reaction of 2-bromo-2-bromomethyl glutaric acid esters with tetraalkylammonium fluoride in HMPA, conveniently provides the corresponding dialkyl (E)-2-bromomethylene derivatives in good yields.

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