Allylation of Aldehydes and Ketones with Allyl Bromide and Tin Promoted by Me₃SiCI and Alcohol

Jing-Yao Zhou Department of Chemistry, Fudan University, Shanghai, 200433, China

Xu-Bo Yao Department of Chemistry, Fudan University, Shanghai, 200433, China

Zhao-Gen Chen Department of Chemistry, Fudan University, Shanghai, 200433, China

Shi-Hui Wu Department of Chemistry, Fudan University, Shanghai, 200433, China

Abstract

Allylation of aldehydes and ketones to give homoallylic alcohols can be carried out successfully with allyl bromide and metallic tin under anhydrous condition. The 64–89% yields of homoallyl alcohols are obtained by addition of chlorotrimethylsilane as a promoter in anhydrous methanol.

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Allylation of Aldehydes and Ketones with Allyl Bromide and Tin Promoted by Me₃SiCI and Alcohol

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Allylation of Aldehydes and Ketones with Allyl Bromide and Tin Promoted by Me3SiCI and Alcohol

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Allylation of Aldehydes and Ketones with Allyl Bromide and Tin Promoted by Me₃SiCI and Alcohol