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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 17
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Original Articles

Phosphinic Acid Analogues of Thiaproline and the Related Heterocyclic Aminophosphinic Acids

Mostafa Hatam Fachbereich Chemie, Universität Oldenburg, P. O. Box 2503, D-26111, Oldenburg, Federal Republic of Germany
&
Jürgen Martens Fachbereich Chemie, Universität Oldenburg, P. O. Box 2503, D-26111, Oldenburg, Federal Republic of Germany
Pages 2553-2559 | Received 22 Dec 1994, Published online: 23 Sep 2006
 
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Abstract

Bis(trimethylsilyl) phosphonite adds in a 1,2 fashion to the C = N bond in 3-thiazolines 3a-d to give after hydrolysis phosphinic acids 5a-d. Starting from 3-oxazines, the corresponding 6a,b phosphinic acids 7a,b were obtained.

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