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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 17
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Original Articles

Oxovanadium-Induced or-Catalyzed Oxidative Allylation of 1,3-Dicarbonyl Compounds with Allylsilanes

Toshikazu Hirao Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamadaoka, Suita, Osaka, 565, Japan
,
Makoto Sakaguchi Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamadaoka, Suita, Osaka, 565, Japan
,
Takuji Ishikawa Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamadaoka, Suita, Osaka, 565, Japan
&
Isao Ikeda Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamadaoka, Suita, Osaka, 565, Japan
Pages 2579-2585 | Received 09 Nov 1994, Published online: 23 Sep 2006
 
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Abstract

The oxidative mono- or di-allylation reaction of 1,3-dicarbonyl compounds with allylsilanes was selectively achieved by treatment with VO(OEt)Cl2.

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