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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 18
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Original Articles

A New Synthesis of 2-Aryl-2-Oxoalkylphosphonates from Triethyl Phosphonoacetate

Dae Young Kim Department of Chemistry, Soonchunhyang University, Onyang P. O. Box 97 Chungnam, 336-600, Korea
,
Myeon Sik Kong Department of Chemistry, Soonchunhyang University, Onyang P. O. Box 97 Chungnam, 336-600, Korea
&
Dae Yong Rhie Department of Chemistry, Soonchunhyang University, Onyang P. O. Box 97 Chungnam, 336-600, Korea
Pages 2865-2869 | Received 31 Jan 1995, Published online: 16 Feb 2007
 
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Abstract

Acylation of triethyl phosphonoacetate using magnesium ethoxide affords acyl phosphonoacetates which, on treatment with catalytic p-TsOH in water, are converted into 2-aryl-2-oxoalkylphosphonates.

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