Studies Toward the Diastereoselective Reduction of 2-Alkoxycarbonyl-2-allyl-cyclopentanone Derivatives with Boron Hydrides

Carlos A. M. Fraga Laboratório de AvaliacęLião de Síntese de Substacirc;ncias Bioativas (L.A.S.S. Bio), Faculdade de Farmácia, Universidade Federal do Rio de Janeiro, C.P. 68006, ZIP-21944190, Rio de Janeiro, R.J., Brazil

Eliezer J. Barreiro Laboratório de AvaliacęLião de Síntese de Substacirc;ncias Bioativas (L.A.S.S. Bio), Faculdade de Farmácia, Universidade Federal do Rio de Janeiro, C.P. 68006, ZIP-21944190, Rio de Janeiro, R.J., Brazil

Abstract

The reduction of 2-alkoxycarbonyl-2-allyl-cyclopentanone derivatives with inexpensive boron hydrides were studied showing that this process depend on chelation factors instead steric ones, affording the isomeric alcohols 2a and 3a with high diastereomeric excess.

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Studies Toward the Diastereoselective Reduction of 2-Alkoxycarbonyl-2-allyl-cyclopentanone Derivatives with Boron Hydrides

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Studies Toward the Diastereoselective Reduction of 2-Alkoxycarbonyl-2-allyl-cyclopentanone Derivatives with Boron Hydrides

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