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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 9
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Original Articles

A Simple Method to Prepare Homoallylic Amines from Secondary Homoallylic Mesylates

Francęoise Hénin Unité “Réarrangements Thermiques et Photochimiques” Associée au CNRS, Université de Reims Champagne-Ardenne, B.P. 347, 51062, Reims Cedex, France
,
Evelyne Mahuet Unité “Réarrangements Thermiques et Photochimiques” Associée au CNRS, Université de Reims Champagne-Ardenne, B.P. 347, 51062, Reims Cedex, France
,
Caroline Muller Unité “Réarrangements Thermiques et Photochimiques” Associée au CNRS, Université de Reims Champagne-Ardenne, B.P. 347, 51062, Reims Cedex, France
&
Jacques Muzart Unité “Réarrangements Thermiques et Photochimiques” Associée au CNRS, Université de Reims Champagne-Ardenne, B.P. 347, 51062, Reims Cedex, France
Pages 1331-1338 | Received 28 Jun 1994, Published online: 23 Sep 2006
 
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Abstract

The nucleophilic substitution by primary amines of secondary homoallylic mesylates easily obtained from corresponding alcohols offers a convenient way to prepare homoallylic amines. The relative low yields in pure compounds is counterbalanced by the simplicity of the procedure.

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