Palladium-Catalyzed Carbonyl Allylation of Aldehydes by Allylic Cyclic Carbonates

Suk-Ku Kang Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea

Dong-Chul Park Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea

Chan-Hee Park Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea

Su-Bum Jang Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea

Abstract

Palladium(O)-catalyzed allylation of aldehydes by allylic cyclic carbonates with SnCl₂ proceeded smoothly to afford 1,3-diols with high diastereocontrol. For the exomethylene cyclic carbonate, allylation with aldehydes furnished 1,4-diols or 1,5-diols depending on amount of aldehydes.

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Palladium-Catalyzed Carbonyl Allylation of Aldehydes by Allylic Cyclic Carbonates

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Palladium-Catalyzed Carbonyl Allylation of Aldehydes by Allylic Cyclic Carbonates

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