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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 21
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Original Articles

Palladium Acetate Mediated Synthesis of 3,4-Benzo and Naphtho-β-Carbolines

A. Jeevanandam Department of Organic Chemistry, University of Madras, Guindy Campus, Madras, 600 025, INDIA
&
P. C. Srinivasan Department of Organic Chemistry, University of Madras, Guindy Campus, Madras, 600 025, INDIA
Pages 3427-3434 | Received 12 Dec 1994, Published online: 23 Sep 2006
 
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Abstract

An efficient synthesis of 2-(N-arylaminomethyl)indole derivatives 5 in good yields in four steps from 2-bromomethyl-3-phenylthio-1-benzenesulfonyl indole1 is reported. Palladium acetate mediated cyclisation of 5 gives benzo and naphtho-ß-carbolines (6 & 7).

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