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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 16
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Original Articles

New Convenient Route to Polyfluoroalkenyltrialkylsilanes and Germanes

Vadim V. Bardin Institute of Organic Chemistry, 630090, Novosibirsk, Russia
,
Luise S. Pressman Institute of Organic Chemistry, 630090, Novosibirsk, Russia
&
Valerii F. Cherstkov Institute of Elementoorganic Compounds, 117813, Moscow, Russia
Pages 2425-2433 | Received 07 Jul 1994, Published online: 04 Jan 2007
 
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Abstract

Perfluoroalkenyl iodides RFCF[dbnd]CFI, CF2[dbnd]CFBr, CC12[dbnd]CC12 and 1-chloroperfluorocycloalkenes react with ClSiMe3 (ClGeEt3) and P (NEt2)3 to yield polyfluoro-alkenyltrialkylsilanes (germanes).

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