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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 20
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Original Articles

A Facile Preparation of Sulphoxides by the Bentonite-Assisted Oxidation of Sulphides with Magnesium Monoperoxyphthalate in an Aprotic Solvent

Masao Hirano Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184, JAPAN
,
Yoshimitsu Ueno Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184, JAPAN
&
Takashi Morimoto Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184, JAPAN
Pages 3125-3134 | Received 24 Feb 1995, Published online: 23 Sep 2006
 
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Abstract

The title oxidation has been investigated in acetonitrile. The substrates examined include alkyl aryl, diaryl, dialkyl, and cyclic sulphides, which afforded the corresponding sulphoxides in good to excellent yields under neutral and mild conditions.

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