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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 20
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Original Articles

Anullmann Ether Reaction Involving an Alkynyl Substrate: A Convergent Route to a Combretastatin Intermediate

Frances Rose Blase Department of Chemistry, Haverford College Haverford, Pennsylvania, 19041-1392
&
Kaustuv Banerjee Department of Chemistry, Haverford College Haverford, Pennsylvania, 19041-1392
Pages 3187-3197 | Received 16 Mar 1995, Published online: 23 Sep 2006
 
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Abstract

We found that we could employ a disubstituted alkynyl halide in an Ullmann ether reaction to produce the cis-alkene intermediate 3 of the combretastatin natural products.

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