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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 11
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Original Articles

Ni(II)-Catalyzed Regio- and Diastereoselective Allylation of Grignards Reagents to Chiral Allylic Cyclic Carbonates

Suk Ku Kang Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea
,
Dong Gyu Cho Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea
,
Chan Hee Park Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea
,
Eun Young Namkoong Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea
&
Joon Seob Shin Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440-746, Korea
Pages 1659-1667 | Received 17 Oct 1994, Published online: 23 Sep 2006
 
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Abstract

Reaction of chiral allylic cyclic carbonates with Grignards reagent in the presence of NiCl2(dppe) as a catalyst afforded the alkylated (E)-allylic alcohols with high regio- and diastereoselectivity.

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