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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 18
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Original Articles

A Facile Route to 4-Dialkylamino-1-(Trimethylsilyl)-1,2-Butadienes

Luc M'Bazé Méva'a Laboratoire de Synthèse Organique, URA CNRS 574, Université de Poitiers, 40, avenue du Recteur Pineau, 86022, Poitiers, France
&
Jacques Pornet Laboratoire de Synthèse Organique, URA CNRS 574, Université de Poitiers, 40, avenue du Recteur Pineau, 86022, Poitiers, France
Pages 3351-3358 | Received 11 Mar 1996, Published online: 21 Aug 2006
 
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Abstract

The synthesis of pure trimethylsilylsubstituted alpha-allenic amines was obtained by reaction of 1,1-bis(trimethylsilyl)-2-propyne with iminium ions, via an aminomethano desilylation process.

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