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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 19
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Original Articles

An Expeditious Synthesis of ALK-2-YN-1-OLS

A. Zwierzak Institute of Organic Chemistry, Technical University (Politechnika), Żwirki 36, 90–924, Łódź, 40, Poland
&
B. Tomassy Institute of Organic Chemistry, Technical University (Politechnika), Żwirki 36, 90–924, Łódź, 40, Poland
Pages 3593-3600 | Received 15 Apr 1996, Published online: 21 Aug 2006
 
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Abstract

A convenient inexpensive preparation of alk-2-yn-1-ols, commencing from terminal alkynes, has been developed. This procedure allows for using paraformaldehyde instead of gaseous formaldehyde for hydroxymethylation of alk-1-ynylmagnesium bromides.

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