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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 1
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Original Articles

New Aspects on the Reactivity of Radicals Generated from 5′-Deoxy-5′-iodoadenosine Derivatives

Edmilson Jose Maria Institut de Chimie des Substances Naturelles, C.N.R.S., 91198, Gif-sur-Yvette, France; Departamento de Química, Universidade Federal de Minas Gerais, 31270, Belo Horizonte, M. G., Brazil
,
Jean-Louis Fourrey Institut de Chimie des Substances Naturelles, C.N.R.S., 91198, Gif-sur-Yvette, France
,
Antonio S. Machado Departamento de Química, Universidade Federal de Juiz de Fora, 36100, Juiz de Fora, M. G., Brazil
&
Malka Robert-Géro Institut de Chimie des Substances Naturelles, C.N.R.S., 91198, Gif-sur-Yvette, France
Pages 27-33 | Received 18 May 1995, Published online: 21 Aug 2006
 
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Abstract

Acrylonitrile can serve as a trap for a 5′-centered radical derived from adenosine affording the corresponding three carbon extended adenosine derivative 8 together with the known 5′,8-cyclization product 9.

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