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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 16
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Original Articles

Reaction of Iodoarenes and Diethyl 2-Pentenedicarboxylate Under the Heck Reaction Conditions. Formation of 3-Aryl-2-pentenedicarboxylates

Seetharamaiyer Padmanabhan Departments of Biochemical Pharmacology and Medicinal Chemistry, School of Pharmacy, State University of New York at Buffalo, Buffalo, NY, 14260, USA
,
Kaustubh V. Gavaskar Departments of Biochemical Pharmacology and Medicinal Chemistry, School of Pharmacy, State University of New York at Buffalo, Buffalo, NY, 14260, USA
&
David J. Triggle Departments of Biochemical Pharmacology and Medicinal Chemistry, School of Pharmacy, State University of New York at Buffalo, Buffalo, NY, 14260, USA
Pages 3109-3113 | Received 11 Mar 1996, Published online: 21 Aug 2006
 
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Abstract

Various substituted iodoarenes underwent arylation with diethyl 2-pentenedicarboxylate under the Heck reaction conditions to give the expected diethyl 3-aryl-2-pentenedicarboxylates. Extension of this reaction to 2-iodoaniline gave the hitherto unreported ethyl quinolin-2-one-4-acetate.

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