Ruthenium-Catalyzed Allylic Substitution of Allylic Cyclic Carbonates

Suk-Ku Kang Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440746, Korea

Dae-Yeun Kim Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440746, Korea

Ryung-Kee Hong Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440746, Korea

Pil-Su Ho Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus, Suwon, 440746, Korea

Abstract

Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh₃₎₂Cl (5 mol %) afforded (E)-allylic alcohol and erythro-β-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to π-allyl ruthenium complex.

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Ruthenium-Catalyzed Allylic Substitution of Allylic Cyclic Carbonates

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Ruthenium-Catalyzed Allylic Substitution of Allylic Cyclic Carbonates

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