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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 17
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Original Articles

1-(Phenylsulfonyl)indol-2-yl Triflate: A Versatile Reagent for the Synthesis of 2-Substituted Indoles

Beno[icaron]t Joseph Institut de Chimie Organique et Analytique, Université d'Orléans, BP 6759, 45067 ORLEANS Cédex 2, France
,
Béatrice Malpel Institut de Chimie Organique et Analytique, Université d'Orléans, BP 6759, 45067 ORLEANS Cédex 2, France
&
Jean-Yves Mérour Institut de Chimie Organique et Analytique, Université d'Orléans, BP 6759, 45067 ORLEANS Cédex 2, France
Pages 3289-3295 | Received 07 Mar 1996, Published online: 21 Aug 2006
 
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Abstract

The palladium-catalysed reaction of 1-(phenylsulfonyl)indol-2-yl triflate 1, with a variety of aryl and heteroaryl boronic acids 2 or vinyl tributylstannane 3 provides a general and an efficient method for the synthesis of 2-substituted indoles 4.

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