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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 15
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Original Articles

Preparation of Diethyl 2-Alkoxymethyl-, 2-Phenylselenomethyl-and 2-Phenylthiomethylmalonate

Jean-Louis Delépine Laboratoire de Synthèse Organique, URA CNRS 482, Faculté des Sciences, B.P. 535, Université du Maine, Le Mans Cedex, 72017, France
,
Pascal Pecquet Laboratoire de Synthèse Organique, URA CNRS 482, Faculté des Sciences, B.P. 535, Université du Maine, Le Mans Cedex, 72017, France
,
Marie-christine Betton Laboratoire de Synthèse Organique, URA CNRS 482, Faculté des Sciences, B.P. 535, Université du Maine, Le Mans Cedex, 72017, France
&
François Huet Laboratoire de Synthèse Organique, URA CNRS 482, Faculté des Sciences, B.P. 535, Université du Maine, Le Mans Cedex, 72017, France
Pages 2819-2829 | Received 31 Dec 1995, Published online: 21 Aug 2006
 
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Abstract

Title compounds were obtained either by alkylation of the sodium derivative of diethyl malonate or by the conjugate addition to diethyl methylenemalonate 4. When reactions with 4 were run in basic medium two successive Michael additions occured.

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