Clay Catalysis: Stork's Alkylation and Acylation of Cyclohexanone Without Isolation of Enamine

Mohamed Hammadi Ecole Nationale Supérieure d'Ingénieurs de Caen I.S.M.R.A., Université de Caen, U.R.A. 480 CANRS, Caen Cedex, F-14050, France

Didier Villemin Ecole Nationale Supérieure d'Ingénieurs de Caen I.S.M.R.A., Université de Caen, U.R.A. 480 CANRS, Caen Cedex, F-14050, France

Abstract

Cyclohexanone and morpholine in the presence of KSF under azeotropic distillation gave 1-morpholinocyclohexene which is alkylated or acylated in situ without isolation of the enamine. The overall yield of these Stork's reactions are better or equivalent to those obtained by isolation of the enamine.

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Clay Catalysis: Stork's Alkylation and Acylation of Cyclohexanone Without Isolation of Enamine

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Clay Catalysis: Stork's Alkylation and Acylation of Cyclohexanone Without Isolation of Enamine

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